Interplay Between Bromine and Iodine in Oxidative Dehydrogenation

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Halogen bonding in hypervalent iodine and bromine derivatives: halonium salts

Halogen bonds have been identified in a series of ionic compounds involving bromonium and iodonium cations and several different anions, some also containing hypervalent atoms. The hypervalent bromine and iodine atoms in the examined compounds are found to have positive σ-holes on the extensions of their covalent bonds, while the hypervalent atoms in the anions have negative σ-holes. The positi...

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ژورنال

عنوان ژورنال: ChemCatChem

سال: 2013

ISSN: 1867-3880

DOI: 10.1002/cctc.201200913